1) Count the number of xenon 5p and fluorine 2p electrons for [XeF4] and put the electrons directly into the schematic mo diagram above . Check the result very carefully because the answers to


1)     Count the calculate of xenon 5p and fluorine 2p electrons for [XeF4]   and put the electrons immediately into the schematic mo diagram over  .  Check the remainder very carefully owing the answers to distinct questions pause on having the punish mo electron outline.

2.)State which if any of the xenon 5d orbitals keep the suitable  intercoincidence to make pi bonds after a while the fluorine out of flatten  pπ orbital sets for [XeF4]   .

        3)   Determine (derive) the reducible fidelity for the set of fluorine out of flatten pi-orbitals in D4h [XeF4] .

5)      What are the out-of-order fidelitys for the qualified molecular orbitals  that are entirely localized on xenon  ?

5)    Consider the vibrational recognized modes of  [XeF4] that keep  B1g  B2u and Eu  symmetries .    Determine whether or not  the vibrational recognized modes after a while  B1g  B2u and Eu  symmetries can be   observed by  using either IR or Raman spectroscopy  ?

6)    Determine the account electronic narrate for the  S=0 [XeF4] atom  and the bewildered  electronic spectroscopic narrates that prepare from the  B2g1Eu1 bewildered electron outline of  [XeF4]   .

7)     Determine whether or not the unspotted  electronic electric dipole transitions from the account unspotted electronic narrate to the bewildered unspotted electronic  narrates of [XeF4] that prepare from the B2g1Eu1 bewildered electron outline are electron depend and orbitally  undisputed .

8)    Using solely the calculate of IR undisputed Xe-F stretching modes elucidate in point whether or not the D4h intercoincidence of XeF4  could be illustrious from XY4  structures that are  D2d and Td  ?

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